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Cake day: November 10th, 2023

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  • Huh, I guess I’d never really looked into the chemistry behind the distinction (which is strange because i am a chemist that loves food), but Maillard reactions involve the proteins, while caramelization involves the sugars. Though both are examples of nonenzymatic browning.

    The good news is that the wiki page for caramelization says that either acidic or basic conditions speed up the caramelization processes, so i think we’re good to go in either front!


  • Heating a solution of aqueous bicarbonate will release carbon dioxide, too. But since we have delicious onions and stuff in there too, let’s walk through my thought process: Baking powder is baking soda + weak acid + cornstarch (to prevent premature reaction). Since the speed-up for the Maillard reaction works by deprotonating amino groups to make them more nucleophilic, the acid-base reaction that releases CO2 when using baking powder will still occur with just baking soda + food (ie: the protiens in the food are acting as the acid). You’re probably right that using baking powder would produce more CO2, or at least produce it faster, but reducing carcinogenic side products for Maillard reactions via CO2 is a low-priority concern for me anyway. Just a fun curiousity that occured to me when reading the wiki page!

    Sorry if my carbon dioxide subscripts don’t work. I don’t think my client supports all the fancy markdown, but i tried my best.


  • Oh shit. That is so cool! I knew lye was used in making pretzels, but i didn’t know it was to get the Maillard browning to happen faster. The wiki page says that one way to reduce the formation of acrylamide, a carcinogen, is by adding carbon dioxide, which is actually released when baking soda is dissolved in water will be released during cooking (edit: see reply chain below for discussion on this point)… IDK for sure if it’s enough to really help, but I’m gonna just roll with it and say it is because delicious food is delicious.


  • Makes sense to me, but there’s still the whole microplastics issue… But honestly, at this point, anything we can do to keep fossil fuels in the ground is a win in my book. I’d love to see us go down that path for plastic needs that are both necessary and supremely difficult to replace with other materials (like medical and laboratory applications), and stop using plasitic entirely for everything else.


  • a lot less. we’re talking ~2 microns (ie: 2 micrometers or 0.002mm). For context, the width of an “average” human hair ranges from 18 to 180 microns (there’s a lot of variability due to age, ethnicity, and lifestyle).

    If you want to see for yourself, you can dissolve the aluminum to leave just the lining (scrub any paint off the outside of the can first). You can use a solution with pH either lower than 3 or higher than 12.5. For context, draino is about 12 on the pH scale, and coca-cola is about 2.5, but the closer you are to neutral, the longer it will take (so while you could theoretically use the soda inside the can, that will take quite a while). There are sulfuric acid drain cleaners that get down into the 1 to 2 pH range (though note that pH is a log scale, so that’s on the order of 10 to 100 times more acidic than the cola and will fuck your shit up if you aren’t careful).

    For whatever you choose to use, be sure to look up safe handling and disposal recommendations before attempting, or simply watch this youtube video instead!


  • Thanks for expanding on the finer points! With inheritance, they also reset the cost-basis when the owner dies, which means that all the capital gains accumulated over the time that the deceased had ownership is never taxed. Like, if I bought stock for $10, die when it’s worth $100, my sister inherits it, and then sells it for $110 a while later, she only pays capital gains on $10 – not $100.

    I don’t think people fully realize how dramatically our tax code rewards capital, at the expense of labor, not just in the broad-strokes (like the tax rate for capital gains vs the rates for income tax brakets) but also in these little details that are easy to overlook. So thanks for the discussion!








  • deo@lemmy.dbzer0.comtoMicroblog Memes@lemmy.worldI can't disagree.
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    5 months ago

    I love the lane assist on my car. It does resist me a little bit in the situations you describe, but it’s not a strong resistance. Just enough to get my attention if i do it by accident, but not enough to hinder me going where i need to go.

    Now i’m curious what the lane assist parameters look like for different makes and models…